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The first two articles can be read directly on this page by clicking on the titles below. You may also read/save the articles by selecting the Adobe pdf Reader or Microsoft Word Icons to the right of each article. If you do not have Adobe pdf reader, it is available as a free download here.

                                  


 

The Phenomena of Moisture in Transformer Oil     
                   
New, re-fined or refurbished Mineral Oil Techon 2007   
                      
Field Trial of Vacuum Dry-out System                                     
Tapchanger Trial

 

 

The Phenomena of Moisture in Transformer Oil

Water in oil appears as an unwanted substance, it is generally accepted that water in microscopic amounts - not gallons- is the cause of more electrical breakdowns than any other impurity.  Moisture constitutes a hazard not only to the insulating qualities of the oil but also to the insulations that are immersed in the oil.

Water may be introduced to the oil by leaking gaskets, poor handling techniques or from the product of natural insulating paper and oil degradation.  As the paper degrades, it produces Carbon Dioxide and Water and as the insulating oil ages, water, acids, sludge and other polar compounds are formed.  So its presence is inevitable during the normal service life of a transformer.

Water is a polar liquid having a high permittivity or dielectric constant it is therefore attracted to areas of strong electric fields.  This sees the internal moisture distributed not uniformly, but in fact potentially concentrating in the most dangerous parts of the system.

It is important to note that water is in a continuous state of movement between the oil and paper insulating system, caused by internal temperature variations due to load and ambient conditions.

Water may be present in four possible forms, they are:

              Free water – That is water that has settled out of the oil in a separate layer.  It is this water which is indicated by a low dielectric breakdown voltage.

              Emulsified water – Or water that is suspended and has not yet settled out into free water (indicated by “caramel” coloured oil).

Nb: A high Power Factor value indicates the possible presence of this suspended water trapped in oil decay products.

              Water in solution – or dissolved in the oil.

              Chemically bound water – Water which is chemically attached to the insulating paper and which is released when oxidized.

The destructive effects of water include:

              Expansion of the paper insulation, altering the mechanical pressure of the transformer clamping system.

              Loss of insulating ability (Dielectric Breakdown Voltage)

              Accelerating paper aging ie triggering decomposition of the fibres in the paper

              Increased corrosion of the core and tank

              Progressive consumption of oil additives

The most dangerous and destructive of these effects is the loss of the oils insulating ability.  This may occur from the following events:

              During periods of high load and at high ambient temperatures, dielectric breakdowns can result from the reduced oil strength with high absolute amounts of water.

              With sudden high loads, water can boil off conductor surfaces and the vapour bubbles can cause dielectric failures as they rise to the top.

              During the cool-down period after high load, the relative saturation of oil will increase.  At its extreme at 100% relative saturation, water will precipitate out and greatly reduce the dielectric strength of the oil.

If oil is oxidized to any extent, any water coming into the transformer will partially be absorbed into the oil decay products (It is this fact which causes old or highly oxidised oil to dissolve more water than new oil).  As the decay products build up in the oil, the surface tension of the water or the interfacial tension between the oil and the water is lowered dramatically.  This heavier decay molecule will then recirculate throughout the entire transformer and will find its way into the paper insulation, or into areas of high electrical intensity thus reducing the insulation resistance. The water saturated oil decay molecule has a preference for the coolest part of the transformer (bottom and fins, leading to corrosion) and areas of highest electrical stress (leading to arcing).

It has been proven that insulating paper with 2% moisture content ages three times faster than one with 1% moisture and thirty times faster with 3% moisture.

It is thus easy to see the importance of maintaining low moisture levels within a transformer to ensure a long and trouble free service life.

 

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TECHCON 2007 PANEL DISCUSSION

“New, re-refined or refurbished? Options for mineral oil”

    Is there any such thing as new mineral oil? Take the carcasses of a few million dinosaurs, a few hundred hectares of trees and sub-vegetation, bury them under hundreds of meters of mud and sludge for a thousand years or so and you have ‘new’ oil. Put it though a refining process and it is readily accepted by engineers everywhere.

     Once that same oil has been in service for 20 or 30 years then passed through a passive microscopic filtration process to remove all contaminants and many of the same engineers refuse to consider its use. Why? Most common answer is, “we don’t want second hand oil in our equipment”. Surely that is an emotive response more suited to the ‘arts sector’ than practical, fact based engineering types?  

     In this brief presentation I hope I can help dismiss some of the myths, cut through some of the sales talk and hopefully begin an objective thinking process in most of you. Firstly;

 What is Oil Refurbishment?

     Refurbishment of oil has been carried out using adsorption by Fullers Earth for decades and is often still used as the final stage in oil refining or re-refining. Adsorption is the tendency of a liquid, gas or small particle to cling to the surface of another substance by physical rather than chemical means.

     Fullers Earth is a hydrated magnesium and aluminum silicate with a unique crystalline structure. Once activated through high temperature, this clay possesses up to 13 hectares of surface area per kilo. Most of the contaminants found in serviced oil are polar in nature and are therefore easily adsorbed by the Fullers Earth.

     When coupled with fine particulate filters (<0.5 micron) plus a high vacuum degasser/dryer system, virtually all oxidation by-products can be removed and the oil returned to original, new oil specifications. The Refurbishment process also removes corrosive sulfur and metals from the oil.

     Once the natural inhibitors consumed in the oxidation process have been replaced by a synthetic anti-oxidant, usually 2,6 Di-tert-butyl-4-Methylphenol (also called DBPC and BHT), the refurbished oil is often more stable than new oil.          

Table 1

Oil Analysis of Refurbishment by Fluidex Fullers Earth treatment process

400kV Transformer, National Grid Company,UK

Test

Before Process

After

Refurbishment

After 1 Year

Operation

After 2 Years

Operation

Moisture ppm

23

8

10

11

Acidity mgKOH/gm

0.20

<0.01

0.01

0.02

Dielectric kV

35

76

71

69

Sludge content %

0.02

<0.01

<0.01

<0.01

Resistivity at 90C

2.5

226

184

160

DDF at 90C

0.095

0.005

0.006

0.009

Oxidation Stability

Total Acid mg

KOH/g sludge% by mass

0.48

2.29

0.16

1.23

0.18

1.30

0.19

1.32

Viscosity at 40C

11.9

11.8

11.8

11.6

Interfacial Tension

25

40

38

36

Aromatic Carbon

10

10

Paraffinic Carbon

48

48

Napthenic Carbon

42

42

Sulphur Content %

0.333

0.320

0.321

Corrosive Sulphur

Positive

negative

negative

negative

Phosphorus ppm

11

ND

ND

ND

Zinc ppm

3

ND

ND

ND

 Does Refurbished oil meet the same specifications as new oil?

Table 2

Test Parameter

Test Method

Refurbished Oil

ESI Bulk Tank

New Oil Specification

Pass/Fail

Moisture (ppm)

D1533

10

<30

Pass

Dielectric BV (kV)

IEC156

85

>60

Pass

Acid Number (mgKOH/gm)

D974

0.01

<0.03

Pass

Interfacial Tension (mN/m)

D971

42.7

>40

Pass

Dielectric Dissipation Factor (% at 25C)

IEC247

0.011

0.05

Pass

 

 Does Refurbished Oil last in service?

Table 3

Case History – In-situ Oil Refurbishment

1978 10MVA 33/6.6kV Wilson Transformer, Serial no. 60580

Date

Acidity